Emma tackles the man she is chasing and finds out he is Neal Cassidy in episode 2x14 "Manhattan".
Dean Fogg meets with Eliza in a park in episode 1x01 "Unauthorized Magic".
Alice and Margo find a former student who knew Charlie's brother in episode 1x03 "Consequences of Advanced Spellcasting".
Constantine lands outside his apartment and avoids his past self before sneaking inside in episode 4x07 "Hell No, Dolly!".
Scully and Mulder talk while driving to Dr. Sanjay's secret apartment in episode 10x02 "Founder's Mutation".
Drake and his friends are arrested by Detective Benedetto outside a club in episode 2x14 "Eternal Sunshine of the Caffeinated Mind".